1－对甲苯磺酰基－3－吖丁啶基甲氧基甲基醚和1，5－二（对甲苯磺酰基）－3，7－二羟基－1，5－二氮杂环辛烷的合成和结构

Svntheses and Structures of 1-Tosvl-3-azetidyl-(methoxymethyl)-ether and 1,5-Ditosyl-3,7-dihydroxy- 1,5-diazacyclooctane

对甲苯磺酰胺二钠盐分别与１，３－二卤化合物和环氧氯丙烷反应，得到两个新的氮杂环化合物，给出可能的反应机理，用红外、核磁、质谱及晶体衍射确定它们的结构。

Two new azacyclo compounds methoxymethyl 3-tosylazacyclobutyl ether( 1)and 1,5-bistosyl-1,5-diazacyclooctane-3,7-diol( 2)have been synthesized by the reactions ofsodium paratosylamide with 1,3-dichloro- 2-propyl methoxymethyl ether(3)and α-epichlorohy-drin(4)respectively,The possible mechanism of the formation of diazacyclooctane derivative isdiscussed.The two compounds are characterized by IR, ￣1H-NMR,MS and X-ray diffarction。