摘要
本文以６，６－二烷基富烯与甲基锂、芳基锂及烯丙基格氏试剂反应所得的取代环戊二烯基负离子与二茂铁甲酰氯反应合成了１０个新的富烯化合物，并通＾１Ｈ ＮＭＲ、ＩＲ及元素分析确定了它们的结构。
The new fulvenes have been synthesized by the reactions of 6,6-dialkylfulvene with methyllithium, aryllithium and allyl Grignard reagent followed by treatment of ferrocene formyl chloride. On the basis of 1H NMR, IR and elemental analysis, their structures were proposed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1995年第3期259-262,共4页
Chinese Journal of Organic Chemistry
关键词
富烯
二茂铁
甲酰化
fulvene, ferrocene formylation, synthesis
