摘要
本文研究了由苯甲酰氨产生的[C_7H_5O]^(2+·)双电荷离子的单分子解离反应及碰撞诱导解离(CID)和电子捕获诱导解离(ECID)反应,讨论了离子的结构及电荷分离过渡态的结构,该离子主要以保持苯环或苯环上H迁移到侧链的结构存在。用在碰撞室上加电压的方法,排除了CID和ECID谱中单分子解离产物的干扰。
The unimolecular neutral losses, unimolecular charge separations,collision induced decompositions (CID ) and electron capture induced decompositions(ECID) of [C_7H_5O] ̄(2+·) doubly charged ions produced from benzyolamide in the ion source of mass spectrometer under 70 eV electron impact were studied in the present work. The decomposing products show that [C_7H_5O] ̄(2+·) mainly exists in two types of structures-intact benzene ring retaining and H migrating structures. The interferences of unimolecular decomposition products in the collision spectra (CID, ECID) were excluded by using the method of application of either a negative or a positive voltage to the collision cell.
出处
《质谱学报》
EI
CAS
CSCD
1995年第3期4-8,共5页
Journal of Chinese Mass Spectrometry Society
基金
国家自然科学基金