摘要
SO2与烷烃在3130高压汞灯辐照下生成光化学烟雾.实验测量了烟雾强度随SO2压力和烷烃压力变化的规律.文中提出的烟雾生成动力学模型较好地反映了这些实验规律,并得到SO2与丙烷、戊烷、己烷生成光化学烟雾速率常数kp2之比,以及它们的物理猝灭速率常数kq2之比.
Photochemical aerosols are formed in SO2-alkane mixture by a high pressure mercury lamp with 3130A radiation.The reltions of photochemical aerosol intensity to partial pressure of SO2 or alkane are measured. A kinetic model is proposed to fit these experimental results.The ratio of photochemical aerosol rate constant kp2 for propane,pentane and hexcane is obtained.