二茂铁基配合物[Zn(η2-O2C(CH2)3Fc)2(4,4′-bpy)2]·2Fc(CH2)3CO2H的合成、晶体结构和电化学性质

Synthesis,Crystal Structure and Electrochemical Properties of a Ferrocenyl Complex[Zn(η2-O2C(CH2)3Fc)2(4,4′-bpy)2]·2Fc(CH2)3CO2H

本文以二茂铁丁酸和4,4′-bpy为配体,合成了一个新的二茂铁基配位化合物[Zn(η2-O2C(CH2)3Fc)2(4,4′-bpy)2].2Fc(CH2)3CO2H(Fc=二茂铁),并用X-射线单晶衍射仪测定了其晶体结构。对该配合物和二茂铁丁酸配体以及二茂铁的电化学性质进行了对比研究。

A new ferrocenyl complex[Zn(η2-O2C(CH2)3Fc)2(4,4′-bpy)2]·2Fc(CH2)3CO2H(Fc=ferrocene) has been synthesized by treating 4-ferrocenylbutanoic acid with Zn ions under the help of 4,4′-bpy ligand,and structurally characterized by x-ray single crystal diffraction.Additionally,electrochemical properties of the complex and 4-ferrocenylbutanoic acid were investigated.