期刊文献+

类-Fenton体系对水中17β-雌二醇的光降解 被引量:7

Light induced degradation of 17β-estradiol in Fenton-like system
下载PDF
导出
摘要 以250W照明金属卤化物灯为光源研究了水中17β雌二醇(E2)在类Fenton体系中的光降解。结果表明,Fe(Ⅲ)/H2O2体系能有效地光降解E2。pH3~6范围内,E2光降解率及反应初始速率随酸度的增大而增大;H2O2初始浓度越大,E2降解率及反应初始速率越大;E2初始浓度越低,E2降解率越高,反应初始速率越低。 Photodegradation of 17β-estradiol (E2) in water induced by a Fenton-like system was investigated under a 250 W metal halide lamp (λ≥313 nm). The results indicated that E2 could be photo-decomposed efficiently in Fe( Ⅲ )/H2O2 system. Over the range of pH 3.0~6.0, the higher acidity of the solution, the higher the degradation efficiency and initial rate of E2 were. The degradation efficiency and initial rate of E2 increased with increasing of initial concentration of H2O2. The lower the initial concentration of E2, the higher the degradation efficiency of E2 was and the lower the initial rate of E2 was.
出处 《环境污染治理技术与设备》 CSCD 北大核心 2005年第7期29-32,共4页 Techniques and Equipment for Environmental Pollution Control
基金 国家自然科学基金资助项目(20177017)
关键词 17β-雌二醇(E2) 类-Fenton体系 光降解 高效液相色谱 17β-estradiol (E2) Fenton-like system photodegradation HPLC
  • 相关文献

参考文献11

  • 1Ternes T. A. , Kreckel P. , Mueller J. Behavious and occurrence of estrogens in municipal sewage treatment plants—Ⅱ. Aerobic batch experiments with activated sludge. Science of the Total Environ. , 1999,225 : 91 - 99.
  • 2Baronti C. , Curini R. , D'Ascenzo G. Monitoring natural and synthetic estrogens at activated sludge sewage treatment plants and in a receiving river water. Environ. Sci. Technol. , 2000, 34. 5059 - 5066.
  • 3Xiao X. Y. , McCalley D. V. , McEvoy J. Analysis of estrogens in river water and effluents using solid-phase extraction and gas chromatography-negative chemical ionisation mass spectrometry of the pentafluorobenzoyl derivatives. J.Chromatogr. A, 2001, 923 : 195 -204.
  • 4Kuch H. M. , Ballschmiter K. Determination of endocrine-disrupting phenolic compounds and estrogens in surface and drinking water by HRGC-(NCI)-MS in the picogram per liter range. Environ. Sci. Technol. , 2001, 35:3201-3206.
  • 5Johnson A. C. , Sumpter J. P. Removal of endocrine-disrupting chemicals in activated sludge treatment works. Environ. Sci. Technol. , 2001, 35:4697 - 4703.
  • 6Liu B. , Liu X. L. Direct photolysis of estrogens in aqueous solutions. Science of the Total Environ. , 2004, 320:269 - 274.
  • 7Ohko Y. , Iuchi K. , Tatsuma T. 17β-estradiol degradation by TiO2 photocatalysis as a means of reducing estrogenic activity. Environ. Sci. Technol. , 2002, 36:4175 -4181.
  • 8Coleman H. M. , Eggins B. R. , Byme J. A. , et al. Photocatalytic degradation of 17β-oestradiol on immobilized TiO2. Appl. Catal. B: Environ. , 2000, 24:L1 - L5.
  • 9Tanizaki T. , Kadokami K. , Shinohara R. Catalytic photodegradation of endocrine disrupting chemicals using titanium dioxide photo semiconductor thin films. Bull. Environ.Contam., 2002, 68:732-739.
  • 10Acero J. L. , Benitez F.J. Degradation of p-Hydrexypheny-Lacetic acid by photoassisted Fenton reation. Water Sci. Technol. , 2001, 44(5): 31-38.

同被引文献163

引证文献7

二级引证文献14

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部