摘要
A new mineral,jichengite ideally 3CuIr_2S_4·(Ni,Fe)_9S_8,was found as a constituent of placer concentrates at a branch of the Luanhe River,about 220 km NNE of Beijing.Its associated minerals are chromite,magnetite,ilmenite,zircon,native gold,iridium,ferrian platinum and osmium.The placer is distributed at places around ultrabasic rock,which hosts chromite orebodies,from which PGM originated.Jichengite occurs commonly as massive or granular aggregates.No perfect morphology of jichengite was observed.It is steel gray and opaque with metallic luster and black streak.It has a Mohs hardness of 5,VHN(d) urn 21.65,H_m 4.465,Hv = 268.1 N/um^2.It is brittle and weakly magnetic. Cleavage {010} is rarely observed.No fracture was observed.Density could not be measured because of its too small grain size.Density(calc.) is 7.003 g/cm^3.Reflect light is reddish-brown,without internal reflections.Anisotropism is distinct with grayish or yellowish white in crossed nicols and bluish violetcopper red in uncrossed nicols.Jichengite shows weak pleochroism and strong bireflectance.The reflectance values in air at the Standard Commission on Ore Mineralogy wavelengths are:38.9,34.3 at 470 nm,38.9,34.5 at 546 nm,39.1,35.3 at 590 nm,39.2,36.8 at 650 nm,parallel-axial extinction.The six strongest lines in the X-ray powder-diffraction pattern[d in A,(I),(hkl)]are:3.00(100)(116),2.80(50) (205),2.48.(50)(208),1.916(40)(2,1,10),1.765(60)(220),1.753(50)(2,0,16).Five chemical analyses carried out,yielding the following results:S 25.76(25.49-5.97),Fe 10.03(9.78-10.31),Co 0.78 (0.75-0.81),Ni 12.48(12.32-12.85),Cu 4.77(4.69-4.83),Ir 46.98(46.14-47.89),sum 100.80wt%,which produced a formula(Cu_(1.556)Fe_(0.976))_(2.532)(Ir_(5.063)S_(10.126))·(Fe_(2.7451)Ni_(4.404)Co_(0.273))_(7.422)S_(6.517).The ideal formula is X_(10)Ir_5S_(17.5),which was calculated by single crystal structure analyses,where X=Cu(Ⅱ)+Fe(Ⅱ)+Ni(Ⅱ) +Co(Ⅱ).The single crystal data were collected using a diffractometer with Mo Kαradiation and a graphite monochromate.The crystal system is trigonal with space group R3m and unit cell parameters a=7.0745(14) A,c=34.267(10) A(The superstructure not found),and the final R Indices[with 564 observed reflections,I>2sigma(Ⅰ)]are R_1=0.0495,wR_2=0.1349.The specimens are deposited in the Geological Museum of China.
A new mineral,jichengite ideally 3CuIr_2S_4·(Ni,Fe)_9S_8,was found as a constituent of placer concentrates at a branch of the Luanhe River,about 220 km NNE of Beijing.Its associated minerals are chromite,magnetite,ilmenite,zircon,native gold,iridium,ferrian platinum and osmium.The placer is distributed at places around ultrabasic rock,which hosts chromite orebodies,from which PGM originated.Jichengite occurs commonly as massive or granular aggregates.No perfect morphology of jichengite was observed.It is steel gray and opaque with metallic luster and black streak.It has a Mohs hardness of 5,VHN(d) urn 21.65,H_m 4.465,Hv = 268.1 N/um^2.It is brittle and weakly magnetic. Cleavage {010} is rarely observed.No fracture was observed.Density could not be measured because of its too small grain size.Density(calc.) is 7.003 g/cm^3.Reflect light is reddish-brown,without internal reflections.Anisotropism is distinct with grayish or yellowish white in crossed nicols and bluish violetcopper red in uncrossed nicols.Jichengite shows weak pleochroism and strong bireflectance.The reflectance values in air at the Standard Commission on Ore Mineralogy wavelengths are:38.9,34.3 at 470 nm,38.9,34.5 at 546 nm,39.1,35.3 at 590 nm,39.2,36.8 at 650 nm,parallel-axial extinction.The six strongest lines in the X-ray powder-diffraction pattern[d in A,(I),(hkl)]are:3.00(100)(116),2.80(50) (205),2.48.(50)(208),1.916(40)(2,1,10),1.765(60)(220),1.753(50)(2,0,16).Five chemical analyses carried out,yielding the following results:S 25.76(25.49-5.97),Fe 10.03(9.78-10.31),Co 0.78 (0.75-0.81),Ni 12.48(12.32-12.85),Cu 4.77(4.69-4.83),Ir 46.98(46.14-47.89),sum 100.80wt%,which produced a formula(Cu_(1.556)Fe_(0.976))_(2.532)(Ir_(5.063)S_(10.126))·(Fe_(2.7451)Ni_(4.404)Co_(0.273))_(7.422)S_(6.517).The ideal formula is X_(10)Ir_5S_(17.5),which was calculated by single crystal structure analyses,where X=Cu(Ⅱ)+Fe(Ⅱ)+Ni(Ⅱ) +Co(Ⅱ).The single crystal data were collected using a diffractometer with Mo Kαradiation and a graphite monochromate.The crystal system is trigonal with space group R3m and unit cell parameters a=7.0745(14) A,c=34.267(10) A(The superstructure not found),and the final R Indices[with 564 observed reflections,I>2sigma(Ⅰ)]are R_1=0.0495,wR_2=0.1349.The specimens are deposited in the Geological Museum of China.
基金
supported by the Program"China's Mineral Species and Systematic Mineralogy Research"with Grant No.201011005-1A,B and C,from The Ministry of Science and Technology of the People's Republic of China
