烯烃高效催化剂及聚合与共聚合的研究

Polymerization and Copolymerization of Olefins with High Active Catalysts

为中山大学高分子研究所烯烃配位聚合研究室在高效Ziegler-Natta催化剂、茂金属催化剂烯烃聚合与共聚合方面部分研究工作的概述。重点叙述了催化剂的设计、过渡金属配合物配体结构及聚合条件对乙烯、丙烯、1-丁烯、丁二烯、苯乙烯等烯烃单体聚合及共聚合活性以及聚合产物结构和分子量的影响。

Researches on polymerization and copolymerization of olefins with Ziegler-Natta metallocene catalyst from our laboratory are summarized in this paper. structure of transition metal catalyst and polymerization conditions on propylene, 1-butene, butadiene and styrene have been discussed. The design for catalyst and homo- and co-polymerizations catalyst and effects of the of ethylene,