摘要
The title complex nBuSn(O)(tsglyO)6·6CHCl3 (tsglyO=N-p-tolysulfonyl-glycinate monoanion) was syn- thesized by the reaction of nBuSn(O)OH with N-p-tolysulfonyl-glycine in 1∶1 molar ratio. The complex was charac- terized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are: a=b=2.7387(4) nm, c= 1.4465(4) nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm-3, F(000)=4878, V=9.396(3) nm3, R1=0.0325, wR2=0.089 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183.
The title complex [^nBuSn（O）（tsglyO）]6·6CHCl3 （tsglyO=N-p-tolysulfonyl-glycinate monoanion） was synthesized by the reaction of ^nBuSn（O）OH with N-p-tolysulfonyl-glycine in 1：1 molar ratio. The complex was characterized by IR, ^1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are： a=b=2.738 7（4） nm, c= 1.446 5（4） nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm^-3, F（000）=4 878, V=9.396（3） nm^3, R1=0.032 5, wR2=0.0898. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC： 274183.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2005年第9期1386-1388,共3页
Chinese Journal of Inorganic Chemistry
基金
湖南省自然科学基金资助项目
衡阳师范学院科研启动基金(No.2004D16)资助项目
