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二氧化锰结构参数与嵌Li^+和H^+的行为 被引量：2

Structural parameters of MnO_2 and its behaviors of Li^+ and H^+ insertion
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摘要 H+与Li+在-γMnO2中的嵌脱行为是由其结构(缺陷)参数决定的。不同晶型的二氧化锰或晶型相同而制备条件不同的二氧化锰,具有不同的结构参数。介绍了有利于嵌脱H+和Li+的-γMnO2结构(缺陷)参数,结构参数与-γMnO2在碱液中的还原机理,以及如何控制制备条件,使之具有某种结构参数等。 The H^＋ and Li^＋ insertion/emersion behaviors of γ-MnO2 were determined by its structural （lacuna） parameters. The various crystalloid forms of MnO2 or the same crystalloid form and various preparation conditions had different structural parameters. The γ-MnO2 structural （lacuna） parameters in favor of the insertion/emersion of H^＋ and Li^＋, the reductive mechanism of γ-MnO2 in alkaline solution and controlling the preparing conditions of MnO2 to get certain structural parmneters were introduced.
作者 夏熙
机构地区 新疆大学应用化学研究所
出处 《电池》 CAS CSCD 北大核心 2005年第4期276-280,共5页 Battery Bimonthly
关键词 二氧化锰 结构参数 Pt参数 Mt参数 LI^+ H^+ γ-MnO2 制备条件 还原机理 缺陷 MnO2 structural parameters Pt parameter Mt parameter
分类号 TM911 [电气工程—电力电子与电力传动]
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参考文献15

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共引文献35

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二级引证文献19

电池
2005年 第4期

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