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1,3,6,11,13,18,28,31-八溴富勒烯-C_(60)LB膜特性及导电性的研究 被引量:1

Studies on Characteristics and Conductivity of 1,3,6,11,13,18,28,31-Octabromofullerene-C_(60)LB Films
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摘要 1,3,6,11,13,18,28,31-八溴富勒烯-C_(60)LB膜特性及导电性的研究叶玉汉,肖玉方(宁波师范学院化学系,宁波,315020)(中国科学院兰州化学物理研究所)关键词1,3,6,11,13,18,28,31-八溴富勒烯,C_(60)L... The molecular behavior of the substituted fullerene 1,3,6,11,13,18,28,31-octabromofullerene(C_(60)Br_8) on the air-water interface is described. It is shown that the highquality LB films of the compound can be constructed onto a variety of solid substrates.An ESR observation exhibits a signal with g=2.002 4 and ΔH=2×10 ̄(-4) T due to C60+Electronic absorption spectra show several strong hands from 224 to 570 nm,the maximum hand is at the position of 570 nm,The electrical conductivity studies suggest that the conductivity is dependent on the layer numbers of LB film and temperature.The thermal activation energy is 0.285 eV.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1996年第2期300-302,共3页 Chemical Journal of Chinese Universities
关键词 1 3 6 11 13 18 28 31-八溴富勒烯 C_60LB膜 导电性 Octabromofullerene-C_(60),LB films,Conductivity
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参考文献3

  • 1肖玉方,J Phys Chem,1994年,98卷,5557页
  • 2肖玉方,Thin Solid Films,1994年,251卷,4页
  • 3肖玉方,Thin Solid Films,1993年,224卷,237页

同被引文献10

  • 1黄春辉,李富友,黄岩谊.光电功能超薄膜[M].北京:北京大学出版社,2004:324--377.
  • 2韩汝珊.富勒烯家族[M].长沙:湖南教育出版社,1994.
  • 3薛群基,张军.分子有序超薄膜及其在摩擦学中的应用[M].沈阳:辽宁科学技术出版社.
  • 4Kratschmer et al. Solid C6o: A New Form of Carbon[J]. Nature, 1990,(347), 354-358.
  • 5H.W.Kroto,J.R.Henth, S.C.Obrien,et al.The structure and properties of fulleyenes [J]. Nature, 1985,(318): 162-165.
  • 6G.Williams, C.Pearson, M.R.Bryce et al. Langmuir-Blodgett films of C60[J]. Thin Solid Films,1993, (209): 150-152.
  • 7Yufang Xiao, Zhongqi Yao, Daosen Jin. High-Resolution Electron Microscopy and Langmuir-Blodgett Electron Diffraction study on the C~0 Films[J]. J.Phys.Chem,1994, (98):5557-5558.
  • 8Toyoko Imae, Yoshito Ikeo. Investigation of fractal aggregation of C6o islands on LB films by AFM[J]. supra- molecular science, 1998,(5):61-65.
  • 9G.G.Siu, Liu Yulong, et al. Surface-enhanced Raman spectroscopy of monolayer C6o Langmuir-Blodgett films[J]. Thin Solid Films, 1996, (274): 147-149.
  • 10张平余,杜祖亮,薛群基.C60 LB膜的原子力显微镜表征[J].电子显微学报,2001,20(4):370-371. 被引量:5

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