乙苯催化氧化合成苯乙酮研究进展

Progress on Ethylbenzene Catalytic Oxidation to Synthesize Acetophenone

综述了乙苯催化氧化合成苯乙酮的研究进展,介绍了杂多化合物、过渡金属络合物、金属原子簇化合物、金属卟啉化合物及分子筛催化剂对乙苯选择氧化反应的催化效果和特点。结果表明,钼钒磷杂多化合物及钴络合物是乙苯催化氧化反应的理想催化剂,具有良好的应用前景。

The research development on behaviors of ethylbenzene catalytic oxidation to synthesize acetophenone was reviewed.The functions and characteristic of catalysts in selective oxidation of ethylbenzene were described for heteropoly compound, transition metal complex, transition metal compound, metal cluster compound, metalloporphyrin compound and molecular sieve catalyst.The results showed that the molybdovanado phosphate heteropoly compound and cobalt complex were good catalysts for the catalytic oxidation of ethylbenzene, and therefore had a satisfactory application foreground.