C-12炸药合成中间体及成品的毛细管电泳分离

Separation of the Intermediates and the Products of C-12 Explosives by Capillary Electrophoresis

用毛细管区带电泳的方法和胶束电动毛细管色谱的方法,分别对C 1 2炸药合成中间体的三个位置异构体和C 1 2炸药成品及其杂质进行了分离。两种实验体系的选择性和重现性都较好,不仅C 1 2炸药合成中间体的三个位置异构体得到了良好的分离,而且C 1 2炸药成品及其杂质也获得了满意的分离结果。

Three isomers of the intermediates produced during the C-12 synthesis process were very difficult to be separated in the past, In this paper, by using mieellar eleetrokinetie capillary chromatography and capillary zone eleetrophoresis respectively, the three isomers were well separated with good selectivity and reproducibility in both experiment systems. Satisfactory separation results were also obtained on the analysis of C-12 explosive and its impurity.