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2-硝基-1-萘酚的合成 被引量：3

Synthesis of 2-Nitro-1-Naphthol
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摘要 以过氧化氢为氧化剂,在碱性条件下氧化2-亚硝基-1-萘酚合成了2-硝基-1-萘酚,优化了反应条件,改进了分离方法,产品收率达到70%以上. 2-Nitro-1-naphthol was prepared from 2-nitroso-1-naphthol in alkaline medium using H202 as oxidant. Reaction conditions were optimized by orthogonal test and the separation procedure was improved. The optimized yield of 2-nitro-1-naphthol reached 70 %.
作者 徐丹 董学亮 刘明 余学军
机构地区 河南省精细化工重点实验室
出处 《化学研究》 CAS 2005年第3期78-79,83,共3页 Chemical Research
关键词 硝基萘酚 亚硝基萘酚 过氧化氢 2-nitro-1-naphthol, 2-nitroso-1-naphthol, hydrogen peroxide
分类号 TS202.3 [轻工技术与工程—食品科学]
  • 相关文献

参考文献13

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同被引文献16

  • 1梁诚.2—萘酚及两种深加工产品合成工艺之改进[J].南化科技信息,1995(4):10-13. 被引量：2
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  • 3Coutts R T, WohllebeM. The synthesis and p roperties of 4 - acetoxy2 -, 3 - dihydro - 3 - oxo - 4H - naphth [ 1.2 - b ] [ 1.4 ] oxazine, an analog of known carcinogenic hydroxamic acids[J]. Can J Chem, 1974, 52(19) : 3432 ~ 3437 .
  • 4Salter, David Anthony, Simkins., et al. Preparation of nitrophenols[P]. US: 3933926, January, 20, 1976 - 20.
  • 5Tsutomu I, ToshikoW, Hisashi T. , et al. Nitrosation of phenolic substrates undermildly basic conditions: selective p reparation of p - quinone monooximes and their antiviral activities[ J]. J Org Chem, 1996, 61 : 2774-2779
  • 6Hodgson H H, Kilner E. Preparation of 2 - and - 4 - nitro -1 - naphthols[J]. J Chem Soc, 1924, 807 -811
  • 7Giuseppe T. Oxidation of nitrosophenols to nitrophenols[J].Atti Accad Sci Ferrara, 1949, 27:93-95
  • 8张澎声编译.精细化工中间体工业生产技术[M].沈阳:染料工业编辑部出版,1996.
  • 9Anderson J R A, Cestoulas A J, Gamett J L.The use of naph- thalene derivatives in inorganic analysis [J].Anala ChimAc- ta, 1959,20:236-242.
  • 10冯亚青主编.精细有机合成化学与工艺学[M].北京:化学工业出版社.2006:190-203,135-154.

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化学研究
2005年 第3期

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