摘要
合成了配合物[Mn(N3)2(Phen)2],并通过X-射线单晶衍射确定了其晶体结构。晶体结构属于三斜晶系,空间群为P1,晶胞参数为:a=0.963 06(19)nm,b=1.342 5(3)nm,c=1.692 9(3)nm;α=87.00(3)°,β=89.00(3)°,γ=86.00(3)°,Z=1。配合物[Mn(N3)2(Phen)2]的每个分子中,锰(II)离子采取六配位的变形八面体几何构型,每个锰原子分别与2个邻菲咯啉的氮原子及2个叠氮基团的氮原子形成配位键。热重分析显示标题化合物有较高的热稳定性。
The complex of[Mn(N3)2 (Phen)2] was synthesized and determined by X-ray single crystal diffraction. It crystalizes in the triclinic system, space group P1^- with lattice parameters, a=0.963 06(19) nm, b=1.342 5(3) nm, c=1.692 9(3) nm; α= 87.00(3)°, β=89.00(3)°,γ=86.00 (3)°,Z=1. Each manganese atom coordinates with the N atoms of the phenanthroline ligands and the N atoms of end-on azide groups, and lies in the distorted octahedral environment. The title compound has higher thermal stability.
出处
《青岛科技大学学报(自然科学版)》
CAS
2005年第4期296-299,共4页
Journal of Qingdao University of Science and Technology:Natural Science Edition
关键词
锰配合物
叠氮基团
晶体结构
热性能
manganese complex
azide group
crystal structure
thermal stability