三硝基苯基氮杂C_(60)衍生物的合成研究

SYNTHESIS OF TRINITROPHENYL AZAFULLEROID

通过C_(60)、苦基氯和叠氮化钠一锅反应的方法，首次将含能的三硝基苯基引入到C_(60)球体结构中，为探索C_(60)在含能材料方面的应用开拓了一条新途径。

Trinitrophenyl azafulleroid was synthesised by a one-pot reaction of C_(60)with picryl chloride and sodium azide.The title compound was isolated by chromatography and identified by FD-MS,UV-vis,IR and (13)~C NMR.C_(60) as a novel allotrope has aroused wide interest in the field of physics and chemistry as well as in materials science.The title compound shows bright prospects in the application of C_(60)and its derivatives in energetic materials.Meanwhile,the paper elaborates on some problems regarding theoretical analyses in the synthesis and characterization.