摘要
采用钌-碘催化体系,由甲酸甲酯和乙烯加氢酯化合成丙酸甲酯,同时还得到了高附加值的副产物3-戊酮和乙酸甲酯.考察了催化剂组成、溶剂以及反应温度、反应时间、乙烯始压等反应条件对反应的影响.
Methyl formate (MF) was used for ethylene hydroesterification to methyl propionate (MP) by using ruthenium-iodides as catalyst system. In the meantime, the valuable diethyl ketone (DEK) and methyl acetate (MA) were obtained as by-products. The influences of various parameters such as catalyst compositions, solvents, reaction temperature and time, initial pressure of ethylene on the reaction were investigated.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
1996年第1期5-8,共4页
Natural Gas Chemical Industry
关键词
甲酸甲酯
乙烯
丙酸甲酯
钌
催化剂
碘
: methyl formate, ethylene, hydroesterification, methyl propionate, ruthenium