摘要
通过模型化合物ArOArCOArArCOArOAr(Ar为苯基或1,4-亚苯基)的全优化结构,得到芳环之间的平均二面角为37.5°,由其结构参数建立了刚性链聚物分子结构与其熔点及玻璃化温度的关系式。据此较好地预测了新品种均聚物的热性能。
The full optimization structure of model compound ArOArCOArArCOArOAr is presented with average dihedral angle of 37.5*,Based on this ,the molecular structure is related to the melting point and glass transition for poly (aryl ether ketone) s and poly(arylether sulphone) s family with rigid molecular chain, The obtained relationship between them is well extended to predict the heat properties of the new family of aromatic homopolymers.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第6期978-982,共5页
Chemical Journal of Chinese Universities
基金
国家"863"高科技项目基金
关键词
链结构
熔点
玻璃化温度
聚醚酮
聚醚砜
Molecular structure of rigid chain,Dihedral angle,Melting point,Glass transition temperature