氨基二苯硒的酰化和缩合反应研究

Studies on the Acylation and condensation of 4-Aminodiphenylselenide

４－氨基二苯硒分别与酸酐和醛进行酰化反应和缩合反应，合成了６种Ｎ－二苯硒胺羰基苯甲酸及１２个Ｎ－二苯硒亚胺化合物。用元素分析、红外光谱、核磁共振谱表征了结构。结果表明在酰化反应和缩合反应中，４－氨基二苯硒与芳伯胺及氨基二茂铁的作用相同，产物结构类似，且均具有生物活性。

Eighteen kinds of organoselenium compounds with biological activities have been synthesized by the acylation and condensation of 4-aminodiphenylselenide with organic anhydrides and aromatic aldehydes. All products are characterized by elemental analysis, IR, and 1H NMR spectra. It is found that 4-aminodiphenylselenide is similar to the aromatic primary amines in both reactions.