含内环化与不含内环化固化理论间的对应关系

Correspondence Rule Between the Curing Theories with Cyclization ann without Cyclization

含内环化与不含内环化固化理论间的对应关系黄旭日，肖兴才，李泽生，孙家，唐敖庆（吉林大学理论化学研究所，长春，１３００２３）关键词内环化，非线性缩聚反应，数量分布函数，高分子矩在研究非线性缩聚反应体系的固化问题时，Ｆｌｏｒｙ和Ｓｔｏｃｋｍａｙｅｒ等［１...

By means of the sol fraction of the type polymerization in which the cyclization is involved, the equilibrium number fraction distribution is obtained by using Lagrange's expansion techniques. Furthermore, a correspondence rule between the curing theories with cyclization and without cyclization is proposed. Using this rule various results of the curing theory with cyclization can be obtained directly from the corresponding ones of the curing theory without cyclization.