摘要
在相转移催化剂（Ｂｕ４ＮＨＳＯ４）作用下，用Ｃｒ（Ⅵ）／Ｃｒ（Ⅲ）及Ａｇ（Ⅱ）／Ａｇ（Ⅰ）双媒质体系对醇类进行间接电氧化。产率为７５．４～９７．５％，电流效率达６０．２～７５．８％。
The selective indirect electrical oxidation of alcohols with Cr(Ⅵ)/Cr(Ⅲ) and Ag(Ⅱ)/Ag(Ⅰ) was studied by using tetrabutylammonium hydrogen sulfate as phase transfer catalyst.The experimental results showed that the yield was 75.4～97.5%,and current efficiency was 60.2～75.8%.This media can be reused.
出处
《合成化学》
CAS
CSCD
1996年第1期93-95,共3页
Chinese Journal of Synthetic Chemistry
基金
河南省自然科学基金
关键词
醇类
选择性电氧化
间接电氧化
相转移催化
Alcohols, Selective oxidation, Indirect electrooxidation, Phase transfer catalyst, Double media.
