6个聚合物胞腔理论状态方程的分子参数比较

A Comparison of the Molecular Parameters for Six Cell Theory Equations of State for Polymer Liquids

利用Ｚｏｌｌｅｒ提供的ＰＢＤ和ＰＩ两种聚合物系列样品的Ｐ－Ｖ－Ｔ数据，对Ｃｅｌｌ、Ｆｌｏｒｙ、ＳＳ、ＳＨＴ、ＳＨＴＦ和ＯＣＭ６个状态方程的分子参数及其随链结构变化的规律作了比较，得到了一些有益的结论。

Molecular parameters and their variation regularity with the chain structure for six equations of state,namely Cell, Flory,SS,SHT,SHTF and OCM were compared using Zoller's PVT data for some serial samples of PBD and PI in this work.As a result,some useful conclusions were obtained which are helpful for the understanding of the EOSs.