N－［2－（2＇－氨基－乙氨基）乙基］草酰甲酯胺合铜（Ⅱ）的合成及其红外光谱研究

STUDY ON THE SYNTHESIS AND IR SPECTRA OF N-[2-(2'-AMINO-ETHYLAMINO)ETHYL]METHYL OXAMIDO COPPER(Ⅱ)

在水溶液中通过Ｎ－［２－（２＇－氨基－乙氨基）乙基］草酰甲酯胺与硫酸铜反应合成了具有单核和桥联多核以及１，１０－邻菲咯琳端接的标题配合物，测定了其红外光谱，并对主要的红外吸收带进行了归属。

The title mono-,polynuclear and extended oxamlde-bridged comPlexes were syn-thesized via reaction of N-[2-(2'-amino-ethylamino)ethyl]methyl oxamide with copper(Ⅱ)sulfate in aqueous solution.The IR spectra of these complexes were measured and the major IR bands were assigned.