过渡金属1,6-己二胺缩双水杨醛Schiff碱配合物的固相合成与表征

The Solid-Phase Synthesis and Characterization of Transition Metal Complex with 1,6-Hexanediamine Schiff Base

在低热固相条件下,氢氧化物M(OH)2(M=Co,Cu,Zn)与1,6-己二胺缩双水杨醛Schiff碱配体(H2L,C20H24N2O2)反应制得了配合物ML。元素分析、X射线衍射、差热-热重分析、红外光谱、紫外光谱和摩尔电导进行表征,确定了配合物的化学组成,推断其结构。

Three new solid transition metal complexes of transition metal hydroxide （M=Co, Cu, Zn） and Shiff base ligand [H2L=C20H24N2O2, N N＇-bis-（salicylidene） 1, 6-hexanediamine] derived from salicylaldehyde and 1,6-hexanediamine were synthesized in low thermal solid phase in the formula of [ML] and characterized by elemental analysis, molar conductance, IR, UV-Vis, XRD, TG-DTG. The compositions of the complexes were confirmed. The new complex＇s probable molecular structure were proposed.