摘要
The title complex [Cp＊Ru（η6-C6H5BPh3）] has been synthesized by the reaction of [Cp＊Ru（H2O）（NBD）]BF4 with H2 and NaBPh4, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P/ with a=11.0610（10）, b=11.2317（10）, c=12.3633（11）A°, a=81.419（2）, β=67.8370（10）, γ=88.370（2）°, V=1405.9（2）,A°^3, Z=2, C34H35BRu, Mr=555.50, Dc=1.312 g/cm3, F（000）=576 and ,μ（MoKa）=0.577 mm^-1. The final R and wR are 0.0559 and 0.1483, respectively for 4365 observed reflections with I〉2σI）. In the title complex, the four phenyl rings bonded to the B atom are deposited in a tetrahedral geometry, and one of the phenyl rings is η^6-bonded to ruthenium.
The title complex [Cp＊Ru（η6-C6H5BPh3）] has been synthesized by the reaction of [Cp＊Ru（H2O）（NBD）]BF4 with H2 and NaBPh4, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P/ with a=11.0610（10）, b=11.2317（10）, c=12.3633（11）A°, a=81.419（2）, β=67.8370（10）, γ=88.370（2）°, V=1405.9（2）,A°^3, Z=2, C34H35BRu, Mr=555.50, Dc=1.312 g/cm3, F（000）=576 and ,μ（MoKa）=0.577 mm^-1. The final R and wR are 0.0559 and 0.1483, respectively for 4365 observed reflections with I〉2σI）. In the title complex, the four phenyl rings bonded to the B atom are deposited in a tetrahedral geometry, and one of the phenyl rings is η^6-bonded to ruthenium.
基金
The work was supported by the National Natural Science Foundation of China (No. 20472023), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry and the Hubei Provincial Science Fund for Distinguished Young Scholars (No. 2003ABB006)
