摘要
The title compound {η^5：η^1-[（2-MeOC6H4）C3H6]CgH6}Li（DME） （DME=1,2-dimethoxy-ethylene） was synthesized by the treatment of 3-[（2-methoxyphenyl）-isopropyl]-indene with 1 equiv, of n-BuLi followed by the recrystallization from a mixed solution of toluene and DME. The compound crystallizes in orthorhombic system, pace group Pbca with a=14.5677（3）, b=15.54670（10）, c=18.7498（3）A°, Z=8, V=4246.45（11）A°^3, Dc=1.127 g/cm^3 and μ（MoKα）=0.072 mm^-1. The coordination geometry can be described as a distorted tetrahedron.
The title compound {η^5：η^1-[（2-MeOC6H4）C3H6]CgH6}Li（DME） （DME=1,2-dimethoxy-ethylene） was synthesized by the treatment of 3-[（2-methoxyphenyl）-isopropyl]-indene with 1 equiv, of n-BuLi followed by the recrystallization from a mixed solution of toluene and DME. The compound crystallizes in orthorhombic system, pace group Pbca with a=14.5677（3）, b=15.54670（10）, c=18.7498（3）A°, Z=8, V=4246.45（11）A°^3, Dc=1.127 g/cm^3 and μ（MoKα）=0.072 mm^-1. The coordination geometry can be described as a distorted tetrahedron.
基金
This work was supported by the National Natural Science Foundation of China (No. 20472001), the program for NCET (NCET-04-590), and the Excellent Young Scholars foundation of Anhui Province (04046079) and a grant from Anhui Education Department (2005hbz06)
