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丁苯胶乳的合成研究 被引量:5

Study on Synthesizing Large Particle Butadine-Styrene Latex by One-step Polymerization
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摘要 以丁二烯和苯乙烯为单体、十二烷基硫醇为乳化剂,通过一步法合成了大粒径丁苯胶乳(SBR)。结果表明:乳化剂浓度、电解质浓度、固含量及单体加入方式是控制丁苯胶乳粒径大小的关键因素。通过适时补加乳化剂,选取适宜的电解质浓度、固含量及采用种子半连续加料方式有利于控制SBR粒径大小及分布。 The influence factors on particle size of butadiene-styrene latex was studied, including emulsifier, electrolyte, initiator, TCS(total solid content). The results showed that emulsifier, electrolyte and TCS were the main influence factors on particle size of SBR latex. 300 nm particle size of SBR latex was produced by adjusting these factors.
出处 《功能高分子学报》 CAS CSCD 北大核心 2005年第3期514-516,共3页 Journal of Functional Polymers
基金 中油公司科研基金项目(2000504)
关键词 乳液聚合 丁苯胶乳 粒径 emulsion polymerization butadiene-styrene latex particle size
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参考文献5

  • 1Ebita Shinya,Oosawa Hirotsugu.Manufacture of rubber latexes with large particle diameter[P].Jpn Kokai Tokkyo Koho JP: 08-27204,1996.
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同被引文献18

  • 1林润雄,宁利红,段良福,董兰国.胶乳附聚法合成大粒径丁苯胶乳[J].胶体与聚合物,2005,23(4):10-11. 被引量:6
  • 2林润雄,宁利红,段良福,董兰国.两步法合成大粒径丁苯胶乳[J].塑料助剂,2005(6):17-18. 被引量:4
  • 3Kashims Shinichi,Hamuro Junji.Production of plasmids containing interleukin-2 coding genes and of interleukin-2 by Escherechiacoli transformants[P].JP:08-27291,1996.
  • 4Ebita,Shinya,Oosawa Hirotsugu.Manufacture of rubber latexes[P].JP:08-27227A,1996.
  • 5Ebita Shinya,Oosawa Hirotsugu.Manufacture of rubber latexes with large particle diameter[P].JP:08-27204,1996.
  • 6Kashims Shinichi, Hamuro Junji. Production of plasmids containing interleukin-2 coding genes and of interleukin-2 by Escherechiacoli transformants: Haruo Jpn Kokai Tokkyo Koho JP,08-272A[P]. 1996.
  • 7Ebita Shinya,Oosawa Hirot sugu. Manufacture of rubber latexes with large particle diameter: Jpn Kokai Tokkyo Koho JP,08-27204[P]. 1996.
  • 8Corpart J M, Candan F. Process for the agglomeration of latex, the agglomerated latex obtained and theuse there 'of in the modification of thermop lastie matrices for making shoekproof:EP 249554[P]. 1987.
  • 9罗立峰.乳化沥青改性剂及其掺配工艺[J].国外公路,1998,18(3):53-55. 被引量:12
  • 10邓锐,王智英,程琛,艾照全,张洪涛.高固含量聚合物乳液流变性研究进展[J].高分子通报,2010(2):52-57. 被引量:10

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