催化合成硫酰氟宏观反应动力学研究

Study on the Macrokinetics of Catalytic Reaction of Suifuryl Fluoride Synthesis

在391～532K,常压条件下于固定床反应器中,研究了硫酰氟合成反应宏观动力学,建立了幂级数型反应动力学模型,并采用常规进化规划算法对实验数据进行了回归和参数估值,获得了硫酰氟合成的宏观动力学方程。统计检验和残差分析表明动力学模型是合适的。

Using a fixed-bed reactor, macrokinetics of the title catalytic reaction was studied. The experiments were operated under follow conditions： temperature range 391- 532 K, atmosphere. Based on the experimental data, the power law kinetics model was obtained and the parameters were evaluated by evolutionary programming. The results calculated from the model were in good agreement with experimental data and the results of statistical test showed that the model was reliable.