双异薄荷醇黄原酸镍的吡啶加合物(英文)

Adduct of Bis(2-isopropyl-5-methylcyclohexyl xanthalato) Nickel(II) with Pyridine

The reaction of homochiral bis(2-isopropyl-5-methylcyclohexyl xanthalato) nickel(II) with pyridine yields an chiral adduct bis(2-isopropyl-5-methylcyclohexyl xanthalato)(dipyridine) nickel(II) (Ⅰ) in which the coordination geometry of the central Ni atom displays a slightly distorted octahedron composed of four S atoms from two xanthalato ligands and two N atoms from pyridine rings. CCDC: 252342.

The reaction of homochiral bis（2-isopropyl-5-methylcyclohexyl xanthalato） nickel（Ⅱ） with pyridine yields an chiral adduct his（2-isopropyl-5-methylcyclohexyl xanthalato）（dipyridine） nickel（Ⅱ） （ Ⅰ ） in which the coordination geometry of the central Ni atom displays a slightly distorted octahedron composed of four S atoms from two xanthalato ligands and two N atoms from pyridine rings. CCDC： 252342.