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铝的水溶液化学特征及其聚合物生成机制 被引量:3

Chemical characteristics of aluminum aqueous solution and the formation mechanism of aluminum polymer
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摘要 聚合氯化铝(PACl)是水处理中应用较广泛的絮凝剂.研究表明,PACl中各种铝聚合物的含量直接影响其絮凝效率.本文综述铝的水解聚合特性以及制备絮凝剂过程中的铝聚合物生成机制,着重介绍了Al13聚合物的结构特性、生成机制以及制备过程中各种因素的影响,为Al13絮凝剂的进一步研究奠定了基础. Much attention has been paid to palyaluminum chloride (PAC1) in recent years because of its higher efficiency and relatively lower costs compared with the traditional coagulants. It has been demonstrated that the aluminum species of PACl are responsible for coagulation efficiency. In this paper, the chemical characteristics of aluminum aqueous solution and the formation mechanism of aluminum polymer species are summarized, and more attention is given to the structure of Al13 polymer, the formation mechanism of Al13 polymer and the influence factors for preparing of PACl with high content of Al13. This paper provides the foundation for Al13 flocculant and its application.
出处 《高技术通讯》 CAS CSCD 北大核心 2005年第9期106-110,共5页 Chinese High Technology Letters
基金 国家自然科学基金,国家高技术研究发展计划(863计划)
关键词 聚合氯化铝 聚合物 生成机制 铝聚合物 机制 化学特征 水溶液 AL13 制备过程 絮凝剂 絮凝效率 polyaluminum chloride (PACl), polymer, formation mechanism
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  • 1Bertsch P M, Parker D R. The Environmental Chemistry of Muminum. 2nd ed. Boca Raton: Lewis publishers, 1996.117-168.
  • 2汤鸿霄.无机高分子絮凝剂的几点新认识[J].工业水处理,1997,17(4):1-5. 被引量:92
  • 3Akitt J W, Farthing A. Aluminum-27 nuclear nragnetic resonance studies of the hydrolysis of aluminum (Ⅲ). Part 4.Hydrolysis using sodium carbonate. J Chem Soc Dalton Trans, 1981:1617.
  • 4Bertsch P M, Thomas G W, Bamhisel R I. Characterization of hydroxy-aluminum solutions by aluminum-27 nuclear magnetic resonance spectroscopy. Soil Sci Soc Am J, 1986, 50:825.
  • 5Kloprogge J T, Don seykens, John W Geus, et al. The effeets of concentration and hydrolysis on the oligomerization and polymerization of M(Ⅲ) as evident from the ^27AI NMR chemieal shifts and linewidths. J Non-Crystalline Solids,1993, 160:144.
  • 6Beach P M. Conditions for Al13 polymer formation in partially neutralized aluminum solutions. Soil Sci Am J, 1987,51:825.
  • 7Thomas F, Masion A, Bottero J Y, et al. Muminum(Ⅲ)speciation with hydroxy carboxylic acids. ^27AI NMR study.Environ Sci Technol, 1993, 27:2511.
  • 8Bottero J Y, Cases J M, Flessinger F, et al. Studies of hydrolyzed aluminum chloride solutions. 1. Nature of aluminum species and composition of aqueous solutions. J Phys Chem,1980, 84:2933.
  • 9Bottero J Y, Tchoubar D, Cases J Met al. Investigation of the hydrolysis of aqueous solutions of aluminum chloride. 2.Nature and structure by small-angle X - ray scattering. J Phys Chem, 1982, 86:3667.
  • 10Bottem J Y, Axelos M, Tchoubar D et al. Mechanism of formation of aluminum trihydroxide from Keggin Al13 polymers.J Colloid Interface Sci, 1987, 117(1):47.

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