摘要
有水合物存在的多相闪蒸计算对于水合物法分离技术非常重要.提出了一个进行气液液水合物四相闪蒸计算的新算法.其中气液(富烃相)液(富水相)三相平衡闪蒸计算采用PatelTeja状态方程,ChenGuo水合物模型用于气相与水合物相平衡的计算.此算法避免了求解复杂的方程组,因此使计算简单化.通过气体与纯水体系和有抑制剂体系的计算检验表明,此算法有很好的计算稳定性.
In this work, a new algorithm for performing vapor-liquid-liquid-hydrate multi-flash calculation was developed. Patel-Teja equation of state was used in performing the vapor-liquid-liquid (V-LHC-Lw) three-phase flash calculation and Chen-Guo two-step hydrate model was used for calculating the vaporhydrate phase equilibria. This method was rather simple as it avoided the complexity of simultaneous solution of a sophisticated group of equations. The proposed algorithm was tested on gas-pure water systems, gas-aqueous solution of alcohol systems, gas-aqueous solution of salt systems and gas system containing no free water. The calculation results showed that the proposed algorithm was stable and effective.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2005年第9期1599-1605,共7页
CIESC Journal
基金
国家自然科学基金项目(20490207
20176028
90210020)
霍英东教育基金项目(81064)~~