Synthesis and Crystal Structure of a Novel Copper (II) Complex with Acetylenedicarboxylate and 2, 2′-Bipyridine

Synthesis and Crystal Structure of a Novel Copper (II) Complex with Acetylenedicarboxylate and 2, 2′-Bipyridine

下载PDF

导出

摘要 The title compound [Cu （ADC）（2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure. The title compound [Cu （ADC）（2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure.

作者 Ming Xing LI Min SHAO Hui DAI Bao Li AN Wen Cong LU Yu ZHU Chen Xia DU

机构地区 Department of Chemistry Department of Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第10期1405-1408,共4页 中国化学快报（英文版）

关键词 Copper complex crystal structure coordination polymer acetylenedicarboxylate acid. Copper complex, crystal structure, coordination polymer, acetylenedicarboxylate acid.

分类号 O614.121 [理学—无机化学]

引文网络
相关文献

参考文献13

1V.V. Pavlishchuk, I. A. Koval, E. Goreshnik, et al., Eur. J. Inorg. Chem., 2001, 297.
2S. Skoulika, P. Dallas, M. G. Siskos, et al., Chem. Mater., 2003, 15, 4576.
3M.X. Li, G. Y. Xie, S. L. Jin, Y. D. Gu, Polyhedron, 1996, 15, 535.
4C. Ruiz-Pérez, Y. Rodríguez-Martín, M. Hernández-Molina, et al., Polyhedron, 2003, 22,2111.
5H.J. Choi, M. P. Suh, Inorg. Chem., 1999, 38, 6309.
6H. Li, M. Eddaoudi, T. L. Groy, O. M. Yaghi, J. Am. Chem. Soc., 1998, 120, 8571.
7Q. Shi, R. Cao, D. F. Sun, M. C. Hong, Y. C. Liang, Polyhedron, 2001, 20, 3287.
8S. Konar, P. S. Mukherjee, M. G. B. Drew, et al., Inorg. Chem., 2003, 42, 2545.
9I. Pantenburg, U. Ruschewitz, Acta Crystallogr. Sect. C, 2002, 58, 483.
10H. Billetter, F. Hohn, I. Pantenburg, U. Ruschewitz, Acta Crystallogr., 2003, C59, 130.

1Guang Dian HAN,Guo Feng HUANG(Institute of Materia Mechca,Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100050).SYNTHESIS　OF　POLYSUBSTITUTED　AROMATIC　COMPOUNDS：2．THE　DIELS－ALDER　REACTION　OF　1－CHLORO　SUBSTITUTED　DIENES　WITH　DIMETHYL　ACETYLENEDICARBOXYLATE[J].Chinese Chemical Letters,1994,5(2):99-100.
2Guang Dlan HAN,Guo Feng HUANG(Institute of Materia Medica, Peking Union Medical College, Chinese Academy of Medical Sciences, Beijing 100060).SYNTHESIS　OF　POLYSUBSTITUTED　AROMATIC　COMPOUNDS　3.THE　DIELS-ALDER　REACTION　OF　PHENYLSELENO　SUBSTITUTED　DIENES　WITH　DIMETHYL　ACETYLENEDICARBOXYLATE[J].Chinese Chemical Letters,1995,6(9):769-770.
3Di Zao Li,Zhong Fei Zheng,Zhi Yun Kang,De Quan Yu.A new method for preparing(2Z,4Z,6Z)-diethyl-4,5-oxepinedicarboxylates and some 1H-azepine analogues[J].Chinese Chemical Letters,2009,20(6):635-639.
4WU Ping,XIA Er-yan,SUN Jing,YAN Chao-guo.Synthesis of Polysubstituted 1,4-Dihydropyridines via Four-component Reactions of Arylamine,Acetylenedicarboxylate, Aromatic Aldehyde and Ethyl Acetoacetate[J].Chemical Research in Chinese Universities,2012,28(4):652-655.
5于明明,赵希娟,傅文甫.Synthesis,Structure and Luminescent Properties of Polymeric Copper(Ⅰ) Halide Complexes Bearing Phosphine and N-donor Bridging Ligands[J].Chinese Journal of Structural Chemistry,2007,26(10):1179-1183.
6LI Ping.Relations Between Stabilities and Structures of Closo Borane Dianions[J].Chinese Journal of Structural Chemistry,2006,25(6):724-734. 被引量：2
7YAO Wei,WANG Xin,XIE Hong-wei,MA Rui-ying,YU Yang,LI Yang-guang.New Supramolecular Networks Based on Paratungstate with N-Donor Bridging Ligands[J].Chemical Research in Chinese Universities,2012,28(3):382-386.
8唐龙,李东升,付峰,王记江,胡怀明,王尧宇.Novel 3-D Supramolecular Architectures Constructed from Zn^2＋ ions, Oxybis（4-benzoate） and Di（2-pyridyl）amine Ligands[J].Chinese Journal of Chemistry,2007,25(11):1641-1645.
9余自力,叶牧,卢丽珍,陈捷.PLASMA POLYMERIZATION OF HEXAMETHYLCYCLOTRISILOXANE[J].Chinese Journal of Polymer Science,1989,7(2):111-118.
10赵斌元.Preparation of Phenolized Calcium Lignosulfonate and Characterization of the Reaction by IR Spectroscopy[J].Journal of Wuhan University of Technology(Materials Science),2001,16(3):12-14.

Chinese Chemical Letters

2005年第10期

浏览历史

内容加载中请稍等...

Synthesis and Crystal Structure of a Novel Copper (II) Complex with Acetylenedicarboxylate and 2, 2′-Bipyridine

参考文献13

相关作者

相关机构

相关主题

浏览历史