甲基丙烯酸三苯墓甲酯和甲基丙烯酸酯类的共聚物在溶液中的螺旋诱导和解旋作用

THE HELIX-INDUCE AND DEROTATION OF THE COPOLYMERIC SEGMENTS OF TrMA AND MMA IN THEIR SOLUTION

甲基丙烯酸三苯墓甲酯和甲基丙烯酸酯类的共聚物在溶液中的螺旋诱导和解旋作用陈传福，刘卫宏，陈永明，任长玉，习复（中国科学院化学研究所北京１０００８０）关键词甲基丙烯酸三苯基甲酯，甲基丙烯酸甲酯，光学活性，螺旋诱导，解旋在手性阴离子复合引发剂存在下，甲基...

The Helix-Induce and derotation of the copolymers of TrMA and MMA havebeen studied in their solution.i.e.the helix-induce of TrMA belieal chain to MMA segment for random copolymers P(TrMA-co-MMA)s and the derotation of MMA segments to itself helix or TrMA helical conformation for two block copolymers,P(TrMA-b-MMA)s.