冲击波处理结晶MgO的ESR研究及对丁烯异构化的影响

Studies on ESR Spectra of Mgo Crystal Treated by Shock Wave and Its Activity for Isomerization of Butene-1

冲击波处理结晶ＭｇＯ的ＥＳＲ研究及对丁烯异构化的影响张菊，郑小明，倪哲民徐康，杨廷录，刘建军（杭州大学催化研究所，杭州，３１００２８）（中国科学院兰州化学物理研究所）关键词冲击波，结晶ＭｇＯ，ＥＳＲ，丁烯异构化由爆炸在凝聚态物质中产生的冲击波是一种以...

After being treated by shock wave,F color centers are formed on MgO crystaland some new signals of free radical appear in the ESR spectrum,The results of isomerization of butene-1 showed that the MgO crystal treated by shock wave exhibits a higherconversion of butene-1 and higher yield of cis-butene due to an increase in defects.