摘要
用溶剂挥发法生长了标题配合物单晶，对其进行了元素分析、熔点测定、红外光谱分析和热分析．结果表明，单氮杂冠醚１，４，７，１０－四氧－１３－氮杂环十五烷与氢离子结合形成铵离子，四个硫氰酸根以氮端与钴（Ⅱ）离子配位形成配阴离子．铵离子与配阴离子通过离子键力结合成标题配合物．
The title complex crystal was obtained by solvent evaporation method. It's composition and properties were determined by elemental analysis and IR.,DTA-TG methods. The azacrown ether, 1, 4, 7,10-tetraoxa-13-aza cyclopentedecane, combines with H+ to form an ammonium. Four NCS- coordinate with Co2+ to form a complex anion. The ammonium and anion are combined by ion-bond force.
基金
山东省教委资助
