摘要
在惰性介质CCl4溶剂中,将C60分别与浓HNO3及NO2反应制备C60硝基化合物,并通过红外光谱、紫外光谱、元素分析等方法确定了C60硝基化合物的结构为C60(NO2)x(OH)y·其中,C60与HNO3反应合成时,x为2~3,y为12~14;与NO2反应合成时,x为3~5,y为12~16·
C60 nitro-derivatives were prepared by reacting C60 in the inert CCl4 solution with concentrated HNO3 and NO2 gas respectively. The products were studied by means of IR, UV and elemental analysis etc. And the formulas were ascertained to be C60(NO2)x(OH)y where x=2~3,y= 12~ 14 or x= 3~5,y= 12~ 16 in the product obtained by concentrated HNO3 or NO2 gas respectively.
出处
《中南工业大学学报》
CSCD
1996年第1期109-112,共4页
Journal of Central South University of Technology(Natural Science)
基金
中国有色金属工业总公司高新技术科研基金
巴陵石油化工公司科研基金
关键词
硝基化合物
合成
性质
碳
C_(60), nitro-derivatives
synthesis
property