摘要
Prophyra-334 was prepared by methanol extraction and HPLC methods from marine algae (dried laver). It is a sunscreen compound that has good absorption of ultraviolet radiations in the wavelength ranges of 200-400 nm. The absorption maximum wavelength of prophyra-334 is at 334 nm, so defined the name. The mo- lar extinction coefficient (ε) of prophyra-334 in aqueous solution at 334 nm wavelength is 4.23×104. The absorp- tion of prophyra-334 in organic solvents differs in aqueous solutions. In polar organic solvents, the absorption maximum wavelength of prophyra-334 has a slight shift toward longer wavelength compared with that in pure water. On the contrary, in inert non-polar organic solvents, the absorption maximum wavelength and the shape of absorption spectra of prophyra-334 are changed. The effects of organic solvents on prophyra-334 stability sug- gested that: (1) the absorbance of prophyra-334 in water is generally constant at temperature of 60°C in 24 h, meaning that prophyra-334 is quite stable in water; (2) the absorbance of prophyra-334 in ethanol and hexane decreases at the same condition. The stability of prophyra-334 in organic solvents is less than that in aqueous solution. In benzene, the prophyra-334 is very instable.
Prophyra-334 was prepared by methanol extraction and HPLC methods from marine algae (dried laver). It is a sunscreen compound that has good absorption of ultraviolet radiations in the wavelength ranges of 200-400 nm. The absorption maximum wavelength of prophyra-334 is at 334 nm, so defined the name. The molar extinction coefficient (ε) of prophyra-334 in aqueous solution at 334 nm wavelength is 4.23×10^4. The absorption of prophyra-334 in organic solvents differs in aqueous solutions. In polar organic solvents, the absorption maximum wavelength of prophyra-334 has a slight shift toward longer wavelength compared with that in pure water. On the contrary, in inert non-polar organic solvents, the absorption maximum wavelength and the shape of absorption spectra of prophyra-334 are changed. The effects of organic solvents on prophyra-334 stability suggested that: (1) the absorbance of prophyra-334 in water is generally constant at temperature of 60℃ in 24 h, meaning that prophyra-334 is quite stable in water; (2) the absorbance of prophyra-334 in ethanol and hexane decreases at the same condition. The stability of prophyra-334 in organic solvents is less than that in aqueous solution. In benzene, the prophyra-334 is very instable.
基金
This study was supported by SRF for ROCS, SEM and Natural ScienceFoundation of Qingdao (No. 04-2-JZ-110)
关键词
海洋
海藻
UV吸收行为
有机溶解
prophyra-334, extraction, isolation, marine algae, organic solvent, UV-absorption