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一类巯基衍生卟啉的合成及其电化学性质研究 被引量：3

Preparation of thiol-derivatized porphyrins and electrochemical behavior of self-assembled monolayers
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摘要 以香草醛、苯甲醛和吡咯为起始原料合成了3种新型尾式巯基卟啉和相应的钴卟啉,用IR、UV-Vis和1HNMR进行了表征.将巯基衍生卟啉自组装在金电极表面,用电化学方法研究了自由碱卟啉和金属卟啉自组膜性质的差异. The three new thiol-derivatized porphyrins are synthesized under acidic conditions by a modified process of Adler preparation of the meso-tetraphenylporphin. The products are characterized by IR, UVVis and ^1HNMR. The voltammetric behavior of gold electrodes modified with neutral free-base and positively charged cobaltous center porphyrin films are investigated using Fe（CN）6^3-/4- as probe species.
作者 康敬万 王永生 卢小泉
机构地区 西北师范大学化学化工学院
出处 《西北师范大学学报（自然科学版）》 CAS 2005年第6期33-37,共5页 Journal of Northwest Normal University(Natural Science)
基金 国家自然科学基金资助项目(20275031 20335030) 西北师范大学科技创新工程资助项目(NWNU-KJCXGC-01)
关键词 巯基卟啉 自组膜 电化学 thiol-derivatized porphyrin self-assembled monolayers electrochemistry
分类号 O657.1 [理学—分析化学]
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参考文献10

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同被引文献33

  • 1刘兵,王志杰,张晓兵,沈国励,俞汝勤.共价固定卟啉作为荧光载体的pH光化学传感器的研究[J].化学传感器,2004,24(2):30-36. 被引量：3
  • 2刘新刚,冯亚青,高博,周立山.新型尾式硫代苯并噻唑基卟啉化合物的合成与表征[J].有机化学,2005,25(5):540-544. 被引量：5
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  • 8WANG Qin, ZHI Fu-peng, WANG Wen-ting, et al. Di- rect electron transfer of thiol-derivatized tetrapbenylpor- phyrin assembled on gold electrodes in an aqueous solu- tion[J]. J. Phys. Chem. C,2009,113(21):9359-9367.
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西北师范大学学报（自然科学版）
2005年 第6期

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