摘要
Calcium magnesium chlorosilicate doped by europium, Ca8Mg（SiO4）4Cl2： Eu^2＋, was prepared by the solid state reaction at high temperature. The compound obtained is pure Ca8Mg（SiO4）4Cl2 phase with cubic structure. Its average particle size is 5 μm, and it has good dispersity and morphological form. The excitation spectrum of Ca8Mg（SiO4）4Cl2： Eu^2＋ is a wide band, which covers from 270 to 480 nm. The emission spectrum is also a wide band peaked at 510 nm. The luminescent intensity reaches to the maximum when the concentration of Eu^2 ＋ is 2%. The wavelength of emission and excitation of the phosphor with various Eu^2 ＋ contents keeps constant. This spectrum range matches violet and blue LED chips very well, and its strong luminescence intensity is suitable for a green phosphor of tricolor phosphor of white light LED.
Calcium magnesium chlorosilicate doped by europium, Ca8Mg（SiO4）4Cl2： Eu^2＋, was prepared by the solid state reaction at high temperature. The compound obtained is pure Ca8Mg（SiO4）4Cl2 phase with cubic structure. Its average particle size is 5 μm, and it has good dispersity and morphological form. The excitation spectrum of Ca8Mg（SiO4）4Cl2： Eu^2＋ is a wide band, which covers from 270 to 480 nm. The emission spectrum is also a wide band peaked at 510 nm. The luminescent intensity reaches to the maximum when the concentration of Eu^2 ＋ is 2%. The wavelength of emission and excitation of the phosphor with various Eu^2 ＋ contents keeps constant. This spectrum range matches violet and blue LED chips very well, and its strong luminescence intensity is suitable for a green phosphor of tricolor phosphor of white light LED.
基金
ProjectsupportedbytheNationalHighTechResearchProgramofChina(2001AAZB3103)
