摘要
采用连续釜式反应器,对NO2氧化二甲基硫醚生成二甲基亚砜的反应进行了实验研究。在假定反应步骤和考虑二甲基亚砜对二氧化氮溶解度影响的前提下,建立了反应的动力学模型,并结合实验数据,对动力学模型进行了参数估值。经统计检验表明,所建立的动力学模型是适当的。
The reaction of dimethyl sulfide oxidized with nitrogen dioxide in liquid phase was investigated in a continuous stirred tank reactor （CSTR）. Based on an assumed reaction scheme and considering the solubility of nitrogen dioxide in dimethyl sulfoxide, the kinetic model of the reaction was built. Moreover, the parameters of kinetic model were obtained by experimental data regression. Through the analysis of statistic test and residual error distribution the kinetic model was convinced to be adequate.
出处
《化学反应工程与工艺》
EI
CAS
CSCD
北大核心
2005年第5期451-455,共5页
Chemical Reaction Engineering and Technology
