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十二硫醇在自交联乳胶涂料中的应用 被引量:3

Application of Dodecyl Mercaptan to Self-Crosslinkable Latex Paint
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摘要 在自交联的丙烯酸酯类乳液体系中,引入链转移剂十二硫醇(DDM)。研究了DDM对乳液体系聚合速度、分子量及其分布、玻璃化转变温度(Tg)、最低成膜温度(MMFT)、乳胶膜的凝胶含量、溶胀比以及力学性能的影响。 Dodecyl mercaptan (DDM) as chain transter agent was introduced into self-crosslinkable acrylate emulsion system. Effects of DDM on polymerization rate, molecular weight, molecular weight distribution, glass-transition temperature (Tg), minimum film formation temperature(MMFT) of the emulsion, gel content, swelling ratio and mechanical performance of the latex film were studied,
出处 《化学建材》 2005年第6期1-4,共4页 Chemical Materials for Construction
关键词 乳液体系 自交联 十二硫醇 聚合速率 MMFT 力学性能 emulsion system self-crosslink dodecyl mercaptan polymerization rate MMFT mechanical performance
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  • 1Winnik M.A.Pinenq P.Kr u ger C.Zhang J,Yaneff P.V.Crosslinking vs.interdiffusion rates in melamine-formaldehyde cured latex coatings:A model for waterborne automotive basecoat[J].J.Coat.Technol.1996.(71):47-60.
  • 2Tamai T.Pinenq P.Winnik M.A.Effect of cross-linking on polymer diffusion in poly (butyl methacrylate-co-butyl acrylate)latex films [J].Macromolecules.1999.(32):6102-6110.
  • 3Zosel A.. Ley G. V. Influence of crossfinklng on struclure, mechanical properlies, and slrength of latex films [J]. Macromolecules. 1993, (26):2222-2227.
  • 4Mohamraed E. S., Daniels L. H., Spvrling A. K., El-Aasset M. S, lsocyan-ate-functionalized latexes: Film formation and tensile properties[J]. J. Appl, Polym. Sci., 1997. (66): 1869-1884.
  • 5Coleman L E., Bork J. F., Wyman D, P., Hoke D. I. Synthesis and polymerization of N[2-(2-methyl-4-oxopentyl)]-acrylamide-A new reactve vinyl monomer [J]. J. Polym. Sci.: Part A, 965, 31 1601-1608.
  • 6Gugliutta L. M., Salazar A. Vega J. R., Meira G. R, Emulsiun polymerization of styrene. Use of n-nonyl nrercaptan for molecular weight control [J]. Polymer, 2001, (42): 2719-2726.
  • 7Plessis C., Arzarnendi G. Alberdi J. M. Agnely M. Leiza J. R.. Asua J, M. Intramolecular chain transfer to polymer in the emulsion polymerization of 2-ethylhexyl acrylate [J].Macromolecules,2001, (34): 6138-6143.
  • 8Plessls C.. Arzamendi G., Leiza J. R., Schoonbrood H. A. S., Charmot D.. Asua J. M. Kinetics and polymer microstructure of the seeded semibatch emulsion copotymerization of n-butyl acrylate and styrene [J]. Macromolecules, 2001, (34):5147-5157.
  • 9Bouvier-Fontes L.Pirri R.Asua J.M.Leiza J.R.Seeded semicontinuous emulsion copolymerization of bityl acrylate with cross-linkers[J].Macromolecules.2005.(37):1164-1171.
  • 10Protzman T.F.Brown G.L.An apparatus for the determination of the minimaum film temperature of polymer emulsions[J].J.Appl.Polym.Sci.1960,(4):81-85.

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