摘要
Under the conditions of tetramethyl ammonia chloride (TMAC) used as starting material, Ti-based Dimensionally Stable Anode (DSA), stainless steel used as cathode and Nafion 900 cation membrane as cell diaphragm, this paper studies the synthesis of tetramethyl ammonium hydroxide (TMAH) by cell diaphragm electrolytic method, examining not only the effects of current density, concentration of starting material and cell temperature, on the product purity and current efficiency, but also the effects of electrolyte circulation rate on the service life of Ti-based DSA. The experiment puts forward an optimum processing condition, and experimental findings show that preparing TMAH by using this technique can obtain a current efficiency 74.7% and get product with a purity greater than 99.9%.
Under the conditions of tetramethyl ammonia chloride （TMAC） used as starting material, Ti-based Dimensionally Stable Anode （DSA）, stainless steel used as cathode and Nafion 900 cation membrane as cell diaphragm, this paper studies the synthesis of tetramethyl ammonium hydroxide （TMAH） by cell diaphragm electrolytic method, examining not only the effects of current density, concentration of starting material and cell temperature, on the product purity and current efficiency, but also the effects of electrolyte circulation rate on the service life of Ti-based DSA. The experiment puts forward an optimum processing condition, and experimental findings show that preparing TMAH by using this technique can obtain a current efficiency 74.7% and get product with a purity greater than 99.9%.
出处
《广东有色金属学报》
2005年第2期566-571,共6页
Journal of Guangdong Non-Ferrous Metals
关键词
四甲基铵
羟化物
电解工艺
合成方法
electrolytic method
tetramethyl ammonium hydroxide（TMAH）
tetramethyl ammonia chloride （TMAC）
