气－固相反应法制备Sm_2Fe_（17）N_y永磁合金过程中氮原子的扩散

DIFFUSION OF NITROGEN ATOMS DURING PREPARING Sm_2Fe_(17)N_y MAGNETS BY GAS-SOLID REACTION METHOD

研究了氮原子在Ｓｍ_２Ｆｅ_（１７）合金中的扩散行为，测定了扩散温度、时间与样品平均氮含量的关系，以及氮原子在样品中的分布；计算了氮原子在Ｓｍ_２Ｆｅ_（１７）合金中的扩散频率因子Ｄ_０和扩散激活能Ｑ，运用扩散Ｆｉｃｋ第二定律计算了氮原子在Ｓｍ_２Ｆｅ_（１７）粉末颗粒内部的分布及其与扩散温度、扩散时间、颗粒尺寸之间的关系．理论计算与实验结果一致．

The diffusion behaviour of N atoms in Sm2Fe17 alloys has been studied. The relationship between the diffusion temperature, the diffusion time with average coneentration of N in samples and the distribution of N concentration in powder particle have been measured. The frequency factor D0 and activation energy Q for N atoms diffusion in Sm2Fe17 particle have been calculated. Using Fick second diffusion law the distribution of N concentration in Sm1Fe17 particles and the relationship between the distribution of N concentration with diffusion temperature, diffusion time and particle size are calculated. The calculated results are consistent with experimental results.