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无甲醛耐久阻燃剂的制备及应用 被引量:13

Preparation and application of formaldehyde free durable flame retardant
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摘要 制备了一种磷系无甲醛阻燃整理剂,研究了阻燃剂的合成条件,红外分析确认了阻燃剂的结构,研究了阻燃剂应用于棉织物的整理工艺。该阻燃剂与多元羧酸及酸性催化剂构成阻燃整理体系,整理后得到无甲醛耐久阻燃棉织物。对整理织物差热分析结果表明,该阻燃剂可大大降低棉织物的热裂解温度,应用时不需要特殊工艺和设备,阻燃效果具有耐久性,可满足多领域对纺织品的阻燃要求。 A formaldehyde free flame retardant was prepared. Its synthetic conditions were studied and chemical structure confirmed by IR. Application of the flame retardant to the treatment of cotton fabrics was investigated. This flame retardant system was based on polycarboxylic acids and acidic catalysts. When it was applied to the finishing of the cotton, a durable flame retarding fabrics without formaldehyde was obtained. The DSC results indicated that this flame retardant can greatly reduce the pyrolytic temperature of cotton fabrics, impart durable flame resistant effect to the fabric, and meet flame resistant requirements of many kinds of textile. Furthermore, no special equipment or finishing technique was required when applying this flame-retardant.
机构地区 青岛大学
出处 《纺织学报》 EI CAS CSCD 北大核心 2005年第6期112-114,共3页 Journal of Textile Research
基金 国家自然科学基金资助项目(50073011)
关键词 无甲醛耐久阻燃剂 制备 阻燃整理 纯棉织物 formaldehyde free durable flame retardant preparation flame resistant finishing cotton fabric
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参考文献5

  • 1Palliser A M, Hoechst U K. Formaldehyde harzards in textile finishing [J]. Colourage, 1997 ,b(2) :279 - 286.
  • 2朱平,王仑,王炳,隋淑英.纯棉织物低甲醛耐久阻燃整理工艺研究[J].印染,2003,29(6):5-7. 被引量:12
  • 3Welch CM. Tetracarboxylic acids as formaldehyde-free durable press finishing agent, Part Ⅰ: catalyst, additive, and durability studies [ J ].Textile Reaserch Journal, 1988,58 (9): 480.
  • 4Zhu Ping,Sui Shuying. A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY-GC-MS [J].Journal of Analytical and Applied Pyrolysis,2004,71:645- 655.
  • 5朱平,隋淑英,王炳,孙铠.阻燃及未阻燃棉织物的热裂解[J].纺织学报,2002,23(6):32-34. 被引量:24

二级参考文献8

  • 1Palliser A M. Hoechst : Formaldehyde Harzards in Textile Finishing, Colourage, 1997,279 - 286.
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