摘要
以4-(反式-4′-正烷基环己基)环己酮和氯甲醚三苯基磷盐为起始原料,经W ittig反应、水解、转型、W ittig反应和氢化反应合成了1-(3,4-二-氟苯基)-2-[反式-4-′(反式-4″-正烷基环己基)环己基]乙烷类液晶,其结构经1H NMR,13C NMR及MS确证。纯化总收率约30%。
1 - （ 3,4-difluorophenyl ） -2- [ warts-4 ＇- （ trans -4＂-n-alkyl cyclohexyl ） cyclohexyl ] ethane type liquid crystal compounds were synthesized from 4- （ trans-4＇-n-alkyl cyclohexyl） cyclohexnone and methoxymethyltriphenyl phosphonium chloride by Wittig reaction, hydrolization, isomerization, Wittig reaction and hydrogenation. The structures were characterized by ^1H NMR, ^13C NMR and MS. The overall yield was about 30% after purification.
出处
《合成化学》
CAS
CSCD
2005年第6期594-596,共3页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(20333060)
关键词
环己酮
环己烷
合成
WITTIG反应
液晶
cyclohexanone
cyclohexane
synthesis
Wittig reaction
liquid crystal
