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Unique Dielectric Behavior of Alkyl Polyglucoside/n-butanol/n-hexane/water System

Unique Dielectric Behavior of Alkyl Polyglucoside/n-butanol/n-hexane/water System
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摘要 The pseudotertiary phase diagram of the microemulsion system alkyl polyglucoside/n-butanol/n-hexane/water was plotted at (30.0±0.1) ℃. The dielectric measurements, including permittivity, conductivity, relaxation strength, characteristic relaxation time, etc,, were applied to investigate the microstructure of the system. Unique dielectric relaxations were observed over the frequency range of 5-10^7 Hz, taking place possibly through an interracial polarization mechanism. According to the results obtained from dielectric spectroscopy, the structures of the microemulsion O/W, BC and W/O were determined, and some dielectric and phase parameters were calculated. The pseudotertiary phase diagram of the microemulsion system alkyl polyglucoside/n-butanol/n-hexane/water was plotted at (30.0±0.1) ℃. The dielectric measurements, including permittivity, conductivity, relaxation strength, characteristic relaxation time, etc,, were applied to investigate the microstructure of the system. Unique dielectric relaxations were observed over the frequency range of 5-10^7 Hz, taking place possibly through an interracial polarization mechanism. According to the results obtained from dielectric spectroscopy, the structures of the microemulsion O/W, BC and W/O were determined, and some dielectric and phase parameters were calculated.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2005年第12期1625-1630,共6页 中国化学(英文版)
基金 Project supported by the Visiting Scholar Foundation of Key Laboratory in Chinese Universities, the National Natural Science Foundation of China (No. 20273010) and the Natural Science Foundation of Shandong Province (No. Y2003B01).
关键词 alkyl polyglucoside MICROEMULSION phase behavior dielectric spectroscopy alkyl polyglucoside, microemulsion, phase behavior, dielectric spectroscopy
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