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Rotation and vibration of diatomic molecule oscillator with hyperbolic potential function 被引量:2

Rotation and vibration of diatomic molecule oscillator with hyperbolic potential function
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摘要 The explicit expressions of energy eigenvalues and eigenfunctions of bound states for a three-dimensional diatomic molecule oscillator with a hyperbolic potential function are obtained approximately by means of the hypergeometric series method. Then for a one-dimensional system, the rigorous solutions of bound states are solved with a similar method. The eigenfunctions of a one-dimensional diatomic molecule oscillator, expressed in terms of the Jacobi polynomial, are employed as an orthonormal basis set, and the analytic expressions of matrix elements for position and momentum operators are given in a closed form. The explicit expressions of energy eigenvalues and eigenfunctions of bound states for a three-dimensional diatomic molecule oscillator with a hyperbolic potential function are obtained approximately by means of the hypergeometric series method. Then for a one-dimensional system, the rigorous solutions of bound states are solved with a similar method. The eigenfunctions of a one-dimensional diatomic molecule oscillator, expressed in terms of the Jacobi polynomial, are employed as an orthonormal basis set, and the analytic expressions of matrix elements for position and momentum operators are given in a closed form.
出处 《Chinese Physics B》 SCIE EI CAS CSCD 2005年第12期2402-2406,共5页 中国物理B(英文版)
基金 Project supported by the National Natural Science Foundation of China (Grant No 90403028).
关键词 diatomic molecule hyperbolic potential matrix elements diatomic molecule, hyperbolic potential, matrix elements
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