摘要
基于二茂铁不同取代基的氧化还原性,利用玻碳电极研究二茂铁及其醇类、醛类、羧酸类的电化学性质。通过循环伏安法探讨了取代基诱导效应和共轭效应对二茂铁电化学性质的影响,并用计时安培法测定了上述8种化合物的扩散系数,探讨了取代基与参数的相关性。
Based on the redox properties of ferrocene, we studied the electrochemical characteristics of ferrocene and its derivatives at glass carbon electrodes. The influence of both resonance and inductive effects on the electrochemied characteristics of ferrocene were investigated by cyclic vohammetry. Diffusion coefficients of eight compounds were determined by chronoamperometry too. The correlation between substituent and parameter was discussed.
出处
《分析试验室》
CAS
CSCD
北大核心
2005年第11期33-36,共4页
Chinese Journal of Analysis Laboratory
基金
国家教育部科技重点基金资助项目(00117)
关键词
二茂铁及其衍生物
循环伏安法
计时安培法
Ferrocene and its derivatives
Cyclic vohammetry
Chronoamperometry
