摘要
本文以钼酸钠和咪唑(C_3H_4N_2,imi)为原料,合成了组成为[Himi]_4[Mo_8O_(26)]·16H_2O的电荷转移配合物。通过元素分析、红外光谱、紫外光谱、热重-差热分析对其进行了初步表征。红外光谱表明,固态配合物的阴、阳离子间存在电荷转移作用;紫外光谱显示,稀水溶液中配合物完全解离,彼此无相互作用。
A new charge-transfer complex, [Himi]4[Mo8O26]·16H2O, was synthesized from sodium molybdate and imidazole （imi）,and characterized by elemental analysis, IR,UV and TG-DTA. The IR spectra of the title compound showed that there is a weak interaction between its organic cation and inorganic anion in solid state, and its UV spectra indicated that it is completely dissociated in dilute aqueous solution.
出处
《光谱实验室》
CAS
CSCD
2005年第6期1142-1145,共4页
Chinese Journal of Spectroscopy Laboratory
基金
孝感学院校立科学研究资助项目
