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燃料电池用质子交换膜的研究进展 被引量:2

Progress in proton exchange membranes for fuel cells
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摘要 对燃料电池用质子交换膜的研究进展进行了简要的概述,特别是从膜材料角度分类.较详细的介绍了全氟化质子交换膜,部分氟化质子交换膜,接枝、交联、共混型质子交换膜等的特性及最新的研究状况,并对其发展前景进行了探讨. Membrane fouling and degradation always restrict the development of membrane technology. In any membrane processes of liquid separated, concentration polarization is a primary reason that results in membrane fouling. Therefore, reducing concentration polarization amounts to relieving membrane fouling. In this article, firstly the phenomenon of concentration polarization on membrane surface, the concentration polarization model and the calculation of mass transfer coefficient are introduced, anf furthermore one ordinary experimentation is provided for predicting the degree of concentration polarization on membrane surface. Then the effects of operational condition on the membrane surface's concentration polarization are analyzed quantitatively, including applied pressure and solution circular flow. Lastly, a little advice on how to reduce membrane fouling that is brought about by concentration polorization is given.
出处 《膜科学与技术》 CAS CSCD 北大核心 2005年第6期75-79,共5页 Membrane Science and Technology
基金 辽宁省教育厅高等学校科学研究项目资助(20040095)
关键词 质子交换膜燃料电池 质子交换膜 聚合物膜材料 电导率 阻醇性能 concentration polarization membrane separation circular flow membrane fouling
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  • 1衣宝廉.燃料电池的原理、技术状态与展望[J].电池工业,2003,8(1):16-22. 被引量:72
  • 2Soner Y, Ekdunge P,Simonsson D, et al. Proton conductivity of Nation 117 as measured by a four electrode AC impendance method [ J ]. J Electrochem Soc, 1996, 143(4) : 1254 - 1259.
  • 3Hodgdon R B. Polyelectrolytes prepared from perfluoroalkylarylmacromolecules[J]. J Polymer Sci, 1968,6:171- 173.
  • 4Basura V I, Beattie P D, Holdcroft S, et al. Solid - state electrochemical oxygen reduction at Pt [ Nafion 117 Pt]BAM3G^TM407 interfaces [ J ]. J Electroanal Chem, 1998,458:1-5.
  • 5Jochen Kerres A. Development of ionomer membranes for fuel cells [J ]. J Membr Sci, 2001,185 : 3 - 27.
  • 6Zaidi S M J,Mikhailenko S D,Robertson G P, et al. Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications [ J ]. J Membr Sci, 2000,173 : 17 - 34.
  • 7Tazi B, Savadogo O. Parameters of PEM fuel - cells based on new membranes fabricated from Nation, Silicotungstic acid and thiophene [ J ]. Electrochim, 2000, 45 : 4329 -4339.
  • 8Nakajima H,Nomura S, Sugimoto T, et al. High temperature proton conductive organic inorganic nanohybrids for polymer electrolyte membrane [ J ]. J Electrochem Soc,2002,149 : 953 - 959.
  • 9Staiti P, Arico A S, Baglio V, et al. Hybrid Nation silica membranes doped with heteropolyacids for application indirect methanol fuel cells [J]. Solid State Ionics, 2001,145:101 - 107.
  • 10Shao Zhi - Gang. Preparation and characterization of hybrid Nafion silicamembrane doped with phosphotungstic acid for high temperature operation of proton exchange membrane fuel cells[J].J Membr Sci,2004,229:43 -51.

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